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CP Freeman Select for Introductory Chemistry for Hillsborough Community College Revision
First EditionKevin Revell
©2020Building a Strong Foundation...Your Way
Introductory Chemistry was developed to take advantage of a digital environment within Sapling Learning to create a more visual, interactive experience for students learning introductory chemistry and to provide a wealth of resources to support various teaching styles. Both the print and digital resources were designed from the ground up and in parallel to create a flexible teaching and learning experience.
Table of Contents
Chapter 1: Foundations
Taxol
Section 1.1 Chemistry: Part of Everything You Do
Section 1.2 Describing Matter
Composition and Structure
Pure Substances and Mixtures
States of Matter
Properties and Changes
Section 1.3 Energy and Change
Section 1.4 The Scientific Method
Chapter 2: Measurement
A Strange Death
Section 2.1 Measurement: A Foundation of Good Science
Scientific Notation: Working with Very Large and Very Small Numbers
Converting from Scientific Notation to Standard Notation
Converting from Standard Notation to Scientific Notation
Calculations Involving Scientific Notation
Units of Measurement
Describing the Quality of Measurements
Describing Precision: Significant Digits
Determining the Number of Significant Digits in a Measurement
Working with Exact Numbers
Using Significant Digits in Calculations
Section 2.2 Unit Conversion
Dimensional Analysis
Problems Involving Multiple Conversions
Converting between Volume Units
Converting Units Raised to a Power
Section 2.3 Density: Relating Mass to Volume
Converting between Mass and Volume
Will It Float?
Section 2.4 Measuring Temperature
Chapter 3: Atoms
Mercury Contamination from Small-Scale Gold Mining
Section 3.1 Atoms: The Essential Building Blocks
Uncovering the Atom: From Democritus to Dalton
Can We See Atoms?
Section 3.2 The Periodic Table of the Elements
Regions of the Periodic Table
Metals, Nonmetals, and Metalloids
Groups (Families) of Elements
Section 3.3 Uncovering Atomic Structure
The Discovery of Charged Particles
The Discovery of the Nucleus
Section 3.4 Describing Atoms: Identity and Mass
Atomic Number and Mass Number
Average Atomic Mass
Section 3.5 Electrons—A Preview
The Bohr Model and the Quantum Model
The Formation of Ions
Chapter 4: Light and Electronic Structure
Edging toward Solar Energy
Section 4.1 The Electromagnetic Spectrum
Wavelength and Frequency
The Energy of a Photon
Section 4.2 Color, Line Spectra, and the Bohr Model
Color and Line Spectra
The Bohr Model
Section 4.3 The Quantum Model and Electron Orbitals
The Uncertainty Principle and the Wave Nature of Electrons
Energy Levels and Sublevels
Section 4.4 Describing Electron Configurations
Valence Electrons and the Octet Rule
Electron Configurations for Larger Atoms
Electron Configurations for Ions
Section 4.5 Electron Configuration and the Periodic Table
Chapter 5: Chemical Bonds & Compounds
An Unexpected Combination: Lithium Carbonate and Bipolar Disorder
Section 5.1 Lewis Symbols and the Octet Rule
Section 5.2 Ions
Cations: Ions with a Positive Charge
Naming Cations
Anions: Ions with a Negative Charge
Naming Anions
Polyatomic Ions
Naming Polyatomic Ions
A Summary of the Common Ions
Section 5.3 Ionic Bonds and Compounds
Ionic Bonds and Ionic Lattices
Predicting Formulas for Ionic Compounds
Naming Ionic Compounds
Section 5.4 Covalent Bonding
Nonmetal–Nonmetal Bonds
Covalent Compounds
Naming Covalent Compounds
Section 5.5 Distinguishing Ionic and Covalent Compounds
Section 5.6 Aqueous Solutions: How Ionic and Covalent Compounds Differ
Section 5.7 Acids – An Introduction
Naming Acids
Binary Acids
Oxyacids
Chapter 6: Chemical Reactions
Lost Cities of the Maya
Section 6.1 Chemical Equations
Balancing Equations
Strategies for Balancing Equations
Equations with Phase Notations
Section 6.2 Classifying Reactions
Section 6.3 Reactions Between Metals and Nonmetals
Section 6.4 Combustion Reactions
Section 6.5 Reactions in Aqueous Solution
Representing Dissociation: Molecular and Ionic Equations
Solubility Rules and Precipitation Reactions
Acid-Base Neutralization Reactions
Acids and Bases
Neutralization Reactions
Chapter 7: Mass Stoichiometry
Process Development
Section 7.1 Formula Mass and Percent Composition
Formula Mass
Percent Composition
How Chemists Measure Formula Mass and Percent Composition
Mass Spectrometry
Elemental Analysis
Section 7.2 Connecting Atomic Mass to Large-Scale Mass: The Mole Concept
Avogadro’s Number and the Mole
Converting between Grams, Moles, and Particles
Section 7.3 The Mole Concept in Balanced Equations
Stoichiometry Problems
Gram-to-Gram Questions
Strategies for Solving Stoichiometry Problems
Calculations with Limiting Reagents
Finding the Leftovers
Section 7.4 Theoretical and Percent Yield
Chapter 8: Energy
The Corn Ethanol Debate
Section 8.1
Units of Energy
Heat and Work in Chemical Changes
Endothermic and Exothermic Changes
The Law of Conservation of Energy
Section 8.2
Specific Heat and Heat Capacity
Calorimetry: Measuring Heat Flow
Coffee Cup Calorimetry
Bomb Calorimetry
Section 8.3
Fuel Value
Reaction Enthalpy
Chapter 9: Covalent Bonding and Molecules
The Shortest Race
Section 9.1 Covalent Molecules
Representing Covalent Structures
Exceptions to the Octet Rule
Drawing Lewis Structures
Section 9.2 Molecules and Charge
Polyatomic Ions and Formal Charge
Drawing Lewis Structures for Polyatomic Ions
Choosing the Best Lewis Structure
Resonance
Section 9.3 Shapes of Molecules
Section 9.4 Polar Bonds and Molecules
Electronegativity and Polar Covalent Bonds
Molecules with Dipoles
Identifying Molecules with a Net Dipole
How Dipoles Affect Properties—A Preview
Chapter 10: Solids, Liquids, and Gases
The North Dakota Boom
Section 10.1 Interactions between Particles
Section 10.2 Solids and Liquids
Ionic Substances
Metallic Substances
Molecular Substances
Dipole–Dipole Interactions
Hydrogen Bonding
London Dispersion Forces
Summarizing Intermolecular Forces
Covalent Networks and Polymers
Section 10.3 Describing Gases Pressure
Measuring Pressure
Section 10.4 The Gas Laws
Boyle’s Law
Charles’s Law
Using Charles’s Law to Find Absolute Zero
Solving Volume–Temperature Problems
Using Charles’s Law
The Combined Gas Law
Avogadro’s Law
The Ideal Gas Law
Mixtures of Gases
A Molecular View of the Gas Laws
Section 10.5 Diffusion and Effusion
Section 10.6 Gas Stoichiometry
Chapter 11: Solutions
The Perfect Cup of Coffee
Section 11.1 Describing Concentration
Concentration by Percent
Percent by Mass and Volume
Mass/Volume Percent
Very Dilute Solutions: ppm and ppb
Molarity
Preparing Solutions of Known Molarity
Preparing Dilute Solutions
Using Square Brackets to Represent Concentration
Section 11.2 Electrolyte Solutions
Electrolyte Concentrations
Colligative Properties
Freezing Point Depression
Boiling Point Elevation
Osmotic Pressure
Section 11.3 Reactions in Solution—A Review and a Preview
Precipitation Reactions
Acid-Base Neutralization Reactions
Metal Displacement Reactions
Section 11.4 Solution Stoichiometry
Gravimetric Analysis
Advanced Stoichiometry Problems
Chapter 12: Acids & Bases
Cocaine: Ruin and Recovery
Section 12.1 Introduction to Acids and Bases
The Arrhenius Definition
Polyprotic Acids
The Brønsted-Lowry Definition
Section 12.2 Acid-Base equilibrium Reactions
Are Conjugate Bases Basic?
Section 12.3 Reactions Involving Acids and Bases
Neutralization Reactions
Reactions of Acids with Metal
Formation of Acids from Nonmetal Oxides
Section 12.4 Acid and Base Concentration
Concentrations of H1 and OH2 in Aqueous Solutions
Math Review: Exponential and Scientific Notation
Connecting [OH2] and [H1]
The pH Scale
Section 12.5 Measuring Acid and Base Concentration
Determining pH in the Laboratory
Acid-Base Titrations
Acid-Base Titrations with Different Coefficients
Section 12.6 Buffers and Biological pH
Chapter 13: Reaction Rates & Equilibrium
The Haber-Bosch Process
13.1 Reaction Rates
How Concentration and Temperature Affect Reaction Rates
How Changes in Energy Affect Reaction Rates
Describing Energy Changes in Chemistry: Reaction Energy Diagrams
Catalysts
13.2 Equilibrium Reactions
13.3 Equilibrium Expressions
Equilibrium Expressions Involving Solvents
Equilibrium Expressions Involving Solids
Solubility Products
Equilibrium Expressions Involving Gases
13.4 Le Chatelier’s Principle
Equilibrium and Concentration
Equilibrium and Temperature
Equilibrium and Pressure
Chapter 14: Oxidation-Reduction Reactions
Volta’s Marvel
14.1 Oxidation and Reduction
Oxidation Numbers
14.2 Types of Redox Reactions
Reactions of Metals with Nonmetals
Combustion Reactions
Metal Displacement Reactions
The Activity Series
Reactions of Metals with Acid and Water
14.3 Half-Reactions and Batteries
Half-Reactions
Batteries
14.4 Balancing Redox Equations
14.5 Other Applications of Redox Reactions
Electroplating
Fuel Cells
Chapter 15: Organic Chemistry and Biomolecules
Robert Grubbs
15.1 Organic Chemistry and the Carbon Cycle
15.2 Covalent Bonding with Carbon and Other Nonmetals
15.3 Drawing Covalent Structures
Condensed Structures
Skeletal Structures
15.4 Major Functional Groups
Hydrocarbon Functional Groups
Alkanes and Cycloalkanes
Alkenes and Alkynes
Aromatic Compounds
Oxygen-Containing Functional Groups
Alcohols and Ethers
Carbonyl Groups
A Summary of Oxygen-Containing Groups
Nitrogen-Containing Functional Groups
15.5 Polymers and Plastics
15.6 Biomolecules—An Introduction
Carbohydrates
Amino Acids and Proteins
Amino Acids
Peptides and Peptide Bonds
DNA
Chapter 16: Nuclear Chemistry
Fukushim
16.1 Nuclear Changes
The Nucleus—A Review
Nuclear Reactions
16.2 Radioactivity
Types of Radioactive Decay
Alpha Decay
Beta Decay
Gamma Decay
Radioactive Decay Series
Half-Life
Health Effects of Radiation Exposure
Measuring Radiation
Common Exposure Levels
Uses of Radioactive Nuclides
Uses in Medicine
Uses in Geology and Archaeology
Carbon-14 Dating of Plant and Animal Remains
Dating of Exposed Rock Surfaces Using Be-10 and Al-26
16.3 Energy Changes in Nuclear Reactions
Mass Defect, Binding Energy, and Einstein’s Famous Equation
Nuclide Stability
16.4 Nuclear Power: Fission and Fusion
Fission
Uranium Enrichment
Fission Reactor Design
Waste from Nuclear Fusion
Fusion
Replicating Fusion on Earth
Are We There Yet?